Hard water locks up herbicide activity
If you are reading this article over a mug of tea, take
a close look and see if there is any evidence of scum on the
surface? If there is, there is a good chance your water supply is
hard, and that could be compromising the performance of your
glyphosate herbicide applications.
That's because the calcium in hard water that is responsible for
furring up the kettle - and reacts with the air and oil in teabags
to create the scum - can bind on to the active ingredient molecules
in a glyphosate herbicide, and render it harmless to the weeds you
are looking to kill, according to Syngenta formulation scientist,
Dr Andrea Hawkins (below).

She warns that some of the active ingredient in standard
glyphosate formulations may be locked up with calcium salts when
tank-mixed in these hard water areas, resulting in highly insoluble
glyphosate calcium that is inactive as a herbicide. "To resolve
this issue, Syngenta developed the System 4 Technology that is
built into Proliance Quattro," reports Dr Hawkins.
"This adds a source of negative sulphate ions which are more
attractive to the positive calcium ions; they readily link up
together and neutralise the solution, creating an inert calcium
sulphate," she explains. "With the positive calcium ions therefore
taken out of the equation, the glyphosate active is unaffected by
the hard water and fully available to control the weeds."
Dr Hawkins points out that hard water supplies affect over half
the land area of England and Wales (above), including around 80% of
the urban environments where Proliance Quattro is most widely
used for weed control on pavements, embankments and amenity areas.
The level of hardness is typically expressed as mg/l of calcium
carbonate, ranging from soft with less than 100 g/l, up to very
hard when it is over 300 g/l. As a rule, the south and east of
England tend to have the hardest water, which gets softer as you go
north. However, throughout the country there are pockets that can
be very different to any local area.
It is made doubly difficult for weed control contractors, who
may be drawing from different water catchments across a wide area
that could have significantly different levels of hardness.
Performance in practice
Weed control specialists Richard Allen and Jamie Page of
Complete Weed Control (CWC) highlight the reliability of control
they consistently achieve with Proliance Quattro. They operate
across an area with some extremely hard water supplies, where the
performance of some glyphosate products has been notably
variable.

Mr Allen ( above) reports one trial he undertook to directly
compare Proliance Quattro with another high-strength premium
glyphsate demonstrated its speed of action and enhanced efficacy.
"The Proliance was a clear five to six days quicker and achieved a
cleaner kill in the time. That gives us greater confidence in the
results we can deliver, and it's certainly appreciated by our
customers."
CWC Contracts Manager, Jamie Page, adds that more city and town
councils are now opting for total herbicide weed control because of
the difficulty in finding staff and the physical costs of manual
hoeing, as well as the damage caused to paving surfaces that allows
more weeds to ingress and makes the problem continually worse.
Operating two CWC franchises, for the Thames Valley and London
South West, the company provides direct weed control services to
local councils and operates as a specialist contractor for overall
facilities managers, as well as full amenity turf management for
businesses and sports amenity sites across the region.
Mr Page (above) believes further budget pressure on local
authorities is going to make value for money even more important in
the future for services such as weed control, that may be viewed by
some as 'non-essential'. He calculates a three or four-spray
herbicide programme over the growing season can deliver significant
cost savings and achieve better results, compared to traditional
hoeing teams. "Any cutbacks in vegetation management are quickly
apparent to the public as a sign of neglect. Our experience is that
where councils have been using the system for successive years, the
overall weed control results get continually better."
The company's system involves Proliance Quattro total herbicide
applied on pavements and urban areas primarily through the
company's six WeedIT automatic spot-treatment machines. Mr Page
highlights they are aiming to apply the minimum possible amount of
active ingredient required to achieve very high levels of control.
"That means we need an inherently high-performance herbicide, with
a good surfactant to achieve complete leaf coverage and to ensure
the product stays on the leaf.
"You can see that virtually all the spray sticks on the leaf, so
there is little or no waste or run off," he adds. The further
advantage of its rapid leaf bonding and quick uptake is its
rainfastness in the event of a shower. "If it does rain, the
operating teams always mark a road map with areas treated in the
preceeding half an hour, so we can go back and check results. With
Proliance Quattro we consistently find that even 10 minutes from
treatment is sufficient to achieve a high level of weed kill after
all but the heaviest rain."
Herbicide treatments will also be applied by knapsack sprayer
or, on larger areas or sports pitches under renovation, with the
company's purpose-built amenity turf sprayer mounted on a Kawasaki
Mule. On gravel paths Proliance Quattro can also be tank-mixed with
a residual herbicide to provide a season-long weed free surface, he
advises.
"From the public perspective the WeedIT machine is a major
advantage because all the spraying is under a covered shroud, so
there's no drift," according to Richard Allen. "And with just
individual weeds targeted by the machine's sensors for
spot-treatment with the appropriate amount of herbicide, we are
typically only treating 20% of the area, compared to spraying the
whole pavement. That means we can use significantly less herbicide
and still achieve a better result and a more cost effective
solution for local authorities."